By José A. C. Broekaert

ISBN-10: 3527301461

ISBN-13: 9783527301461

This thoroughly revised moment variation of the normal paintings has been multiplied by way of a few twenty percentage to incorporate additional information at the newest advancements and new gear. specifically, sections were extra on microplasmas and new forms of spectrometers, whereas that at the swiftly increasing box of speciations with useful examples from existence and environmental sciences were included.

nonetheless in a single convenient quantity, the ebook covers all of the vital smooth facets of atomic fluorescence, emission and absorption spectroscopy in addition to plasma mass spectroscopy in a effortlessly understandable and practice-oriented demeanour. an intensive rationalization of the actual, theoretical and technical fundamentals, instance purposes together with the concrete execution of research and finished cross-references to the most recent literature permit even novices quick access to the methodologies defined.

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Extra info for Analytical atomic spectrometry with flames and plasmas

Example text

They can be obtained from the intensity distribution for the rotational lines in the rotation±vibration spectra, as described by Eqs. (83±90). The molecules OH, CN etc. g. Refs. [21±23]). The gas temperature is determined by the kinetic energy of the neutral atoms and the ions. It can be determined from the Doppler broadening of the spectral lines, as described by Eq. (49). g. shown for the case of glow discharges in Ref. [24]. Whereas the rotational and the gas temperature are particularly relevant to the evaporation processes in the plasma, the electron temperature, being a measure of the kinetic energy of the electrons, is relevant to the study of excitation and ionization by collisions with electrons.

72). Because with the ``two-line method'' using lines of the same ionization level for the determination of temperatures, it is dicult to ful®l all conditions necessary to obtain highly accurate values [see Eqs. (38) and (39)], a method was developed that enables the plasma temperature to be determined from intensities of lines belonging to di€erent ionization levels. When Ii is the intensity of an ion line and I the intensity of an atom line (in general both lines have to belong to two adjacent 21 22 1 Basic Principles ionization levels), one can write: Ii aI ˆ 2…Ai gi li aAgl†  ‰…2pmkT† 3a2 a…h 3 †Š  …1ane †  …T 3a2 †  exp‰À…Ei À E ‡ Ei À DEi †a…kT†Š …78† DEi is a correction for the ionization energy of the lowest level.

1 Atomic structure The basic processes in optical atomic spectrometry involve the outer electrons of the atomic species and therefore its possibilities and limitations can be well understood from the theory of atomic structure itself. On the other hand, the availability of optical spectra was decisive in the development of the theory of atomic structure and even for the discovery of a series of elements. With the study of the relationship between the wavelengths of the chemical elements in the mid-19th century a fundament was obtained for the relationship between the atomic structure and the optical line emission spectra of the elements.

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